Cut the chuck roast into 4-5 large chunks.
In a large bowl, add the adobo seasoning, 1/2 teaspoon of the pepper, 1 teaspoon of the cumin, the garlic powder, 1 teaspoon of the dried oregano, 1 teaspoon of the paprika, and the sazón seasoning and whisk to combine.
Add the beef pieces to the spice mixture and rub until they are well-seasoned.
Add the beef pieces to a large pressure cooker and set the pressure cooker to sauté mode.
Sear the beef pieces until golden-brown, about 2-3 minutes per side.
Transfer the beef pieces to a plate.
Add the oil to the pressure cooker and heat.
Add the onions and the bell peppers to the hot oil and cook, while stirring, until very soft, about 10-15 minutes.
Add the browned beef pieces, the garlic cloves, the remaining oregano, the remaining cumin, the remaining paprika, the smoked paprika, the ground cloves, the allspice, the white wine, the crushed tomatoes and their juices, the tomato paste, the chicken broth, the bay leaves, the salt, and the extra pepper to the pressure cooker and stir to combine.
Seal the pressure cooker and cook on high pressure for 90 minutes.
Carefully release the pressure, then carefully remove the lid.
Optionally, using two forks, shred the beef. Shredding the beef is the traditional way to serve Ropa Vieja, but it is not necessary.
Switch the pressure cooker to the sauté mode and add the olives and the capers.
Cook the beef mixture, while stirring, until fragrant, heated through, and incorporated, about 10 minutes.
Taste the beef mixture and season it with more of the salt and more of the pepper, as needed.
Serve.